Thiete Dioxides as Templates Towards Twisted Scaffolds and Macrocyclic Structures
Thiete Dioxides as Templates Towards Twisted Scaffolds and Macrocyclic Structures
复制标题
DOI：
10.1002/chem.201905751
复制
发表时间：
2020-04-28
影响因子：
4.3
通讯作者：
Didier, Dorian
中科院分区：
文献类型：
--
作者：
Baumann, Andreas N.;Reiners, Felix;Didier, Dorian
二氧化钛单元被用作通过C-H活化策略进一步功能化的模板。使用简单的二氧化钛构建块，合成了一个新的轴向手性分子库，其稳定性归功于固体中的静电相互作用。类似的起始材料进一步参与了环状三聚体结构的形成，为前所未有的大环体系开辟了途径。
Thiete dioxide units have been employed as a template for further functionalization through C-H activation strategies. Using simple thiete dioxide building blocks, a new library of axially chiral molecules has been synthesized that owe their stability to electrostatic interactions in the solid state. Similar starting materials were further engaged in the formation of cyclic trimeric structures, opening the pathway to unprecedented macrocyclic ring systems.