Synthesis of reactive copolyesters derived from isophthaloyl chloride, bisphenol a, and aliphatic diols with additional reactive groups

Synthesis of reactive copolyesters derived from isophthaloyl chloride, bisphenol a, and aliphatic diols with additional reactive groups
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由间苯二甲酰氯、双酚 A 和带有附加反应基团的脂肪族二醇衍生的反应性共聚酯的合成

DOI:
10.1002/pola.1995.080331209
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发表时间:
1995
期刊:
影响因子:
--
通讯作者:
Shigeo Nakamura
Shigeo Nakamura
中科院分区:
--
文献类型:
--
作者:
Chonghui Wang;Shigeo Nakamura

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Copolycondensation of isophthaloyl chloride, bisphenol A, and aliphatic diols with additional reactive groups were performed in the presence of triethylamine by a trimethyl phosphate/cyclohexane organic/organic interfacial method. The composition of diol and bisphenol A residues in the resulting copolyesters is very close to that in the feed from the initial stage of reaction. The resulting copolyesters with reactive groups can be used for the preparation of various functional polymers. The mechanism of an organic/organic interfacial polycondensation was also discussed.