Use of fluorine kinetic isotope effects in the study of steric effects in nucleophilic aromatic substitution reactions
Use of fluorine kinetic isotope effects in the study of steric effects in nucleophilic aromatic substitution reactions
复制标题
利用氟动力学同位素效应研究亲核芳香取代反应中的空间效应
DOI：
10.1021/jo981301i
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发表时间：
1998
影响因子：
3.6
通讯作者：
O. Matsson
中科院分区：
文献类型：
--
作者：
J. Persson;O. Matsson
为了探讨空间位阻效应对亲核芳香取代(SNAR)反应机理的影响，测定了离基氟的动力学同位素效应(FKies)。
Leaving group fluorine kinetic isotope effects (F KIEs) have been determined in order to probe the influence of steric effects on the mechanism of the nucleophilic aromatic substitution (SNAr) reac ...