ORGANIC DEUTERIUM COMPOUNDS: XIX. SYNTHESIS OF SOME DEUTERATED LAURIC ACIDS AND THEIR METHYL ESTERS
ORGANIC DEUTERIUM COMPOUNDS: XIX. SYNTHESIS OF SOME DEUTERATED LAURIC ACIDS AND THEIR METHYL ESTERS
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有机氘化合物：XIX。
DOI：
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发表时间：
1958
期刊：
影响因子：
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通讯作者：
L. C. Leitch
中科院分区：
文献类型：
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作者：
M. Isabelle;L. C. Leitch
本文叙述了羧基、末端甲基和α-亚甲基以及它们的各种组合的氘代月桂酸的合成。本文还报道了两个卤代均聚物与烯烃的加成反应的例子，并描述了烷基卤与乙炔基银的反应。一种机制，涉及一种新的类型的自由基的假设。
The synthesis of lauric acids deuterated in the carboxyl, the terminal methyl, and the α-methylene groups and in various combinations of these is described. The methyl and methyl-d3 esters of each of the acids were also prepared.Two further examples of homolytic halide addition to olefins are reported.The reaction between alkyl halides and silver acetylides is described. A mechanism involving a new type of free radical is postulated.