Mirror-Image Magnetic Circularly Polarized Luminescence from Perovskite (M+Pb2+Br3, M+ = Cs+ and amidinium) Quantum Dots
Mirror-Image Magnetic Circularly Polarized Luminescence from Perovskite (M+Pb2+Br3, M+ = Cs+ and amidinium) Quantum Dots
复制标题
钙钛矿（M Pb2 Br3，M = Cs 和脒）量子点的镜像磁圆偏振发光
DOI：
10.1002/ejic.202101066
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
Y.
中科院分区：
文献类型：
--
作者：
Amasaki;R.; Kitahara;M.; Kimoto;T.; Fujiki;M.; Imai;Y.
室温下，在1.7T的南北向上磁场作用下，两种非手性可溶性抗磁性钙钛矿-Pb-量子点在甲苯溶液中均出现了双磁性圆偏振发光（MCPL）和光致发光（PL）谱的红移. MCPL的大小，gMCPL，大约是|gMCPL| =10− 3，波长范围为480-580 nm。MCPL光谱的波长和符号可以分别通过钙钛矿组成原子的类型和磁场的方向来控制。
Ambidextrous magnetic circularly polarized luminescence (MCPL) and redshift in photoluminescence (PL) spectra are observed from two types of achiral soluble diamagnetic perovskite‐Pb‐quantum dots in toluene solution at room temperature, when subjected to external north‐up and south‐up magnetic fields of 1.7 T. The magnitude of the MCPL,gMCPL, is in the order of |gMCPL|=10−3within a wavelength range of 480–580 nm. The wavelength and the sign of the MCPL spectra can be controlled by the types of perovskite constituent atom and the direction of the magnetic field, respectively.