Modular self-assembled multiporphyrin cages with tunable shape
Modular self-assembled multiporphyrin cages with tunable shape
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DOI：
10.1039/c2cc31420g
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Iengo, Elisabetta
中科院分区：
文献类型：
--
作者：
Alessio, Enzo;Casanova, Massimo;Iengo, Elisabetta
通过将一个双锌卟啉金属配合物（1）与适当的多面体N-连接体（三角平面tpt或十字形卟啉4 '-TPyP和4'-TPhPyP）自组装，得到了三个新的分子笼（2）和两个尺寸逐渐增大的三角形盒子（3，4），它们含有多达10个卟啉。
Three new molecular cages-a trigonal prism (2) and two cubic-shaped boxes of increasing size (3, 4)-featuring as many as 10 porphyrins were obtained in quantitative yields by self-assembly of a single bis-zincporphyrin metallacycle (1) with appropriate polytopic N-linkers: the trigonal planar tpt or the cruciform porphyrins 4'-TPyP and 4'-TPhPyP.