THE CRYSTAL PACKING OF BIS(2,2'-DIPYRIDYLAMIDO)COBALT(II), CO(DPA)2, IS STABILIZED BY C-H...N BONDS: ARE THERE ANY REAL PRECEDENTS?
THE CRYSTAL PACKING OF BIS(2,2'-DIPYRIDYLAMIDO)COBALT(II), CO(DPA)2, IS STABILIZED BY C-H...N BONDS: ARE THERE ANY REAL PRECEDENTS?
复制标题
双(2,2-二吡啶氨基)钴(II), CO(DPA)2 的晶体堆积通过 C-H...N 键稳定：有任何真实的先例吗？
DOI：
10.1039/a702948i
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发表时间：
1997
影响因子：
4.9
通讯作者：
C. A. Murillo
中科院分区：
文献类型：
--
作者：
F. Cotton;L. Daniels;G. Jordan;C. A. Murillo
Co（dpa）的晶体学研究
2
揭示了
假四面体分子堆叠在一起形成一维
分子通过重要的
C-H···N相互作用;
C···N分离为3.41（3）A，
氢原子是177（2）°。
A crystallographic study of Co(dpa)
2
reveals that the
pseudo-tetrahedral molecules stack together to form a one-dimensional
ribbon with the molecules linked together through significant
C–H···N interactions; the
C···N separation is 3.41(3) A and the angle at
the hydrogen atom is 177(2)°.