Thioaldehyde S-oxide (monosubstituted sulfines) from thioacylsilane S-oxides. Synthesis and fluorine- and acid-induced Z/E isomerization. 2
Thioaldehyde S-oxide (monosubstituted sulfines) from thioacylsilane S-oxides. Synthesis and fluorine- and acid-induced Z/E isomerization. 2
复制标题
来自硫代酰基硅烷 S-氧化物的硫代醛 S-氧化物（单取代的亚砜）。
DOI：
10.1021/jo00299a012
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发表时间：
1990
影响因子：
3.6
通讯作者：
P. Zani
中科院分区：
文献类型：
--
作者：
G. Barbaro;A. Battaglia;P. Giorgianni;B. Bonini;G. Maccagnani;P. Zani
芳族和脂族的，不可烯硫醇化的硫代醛S-氧化物（单取代的亚砜）由相应的硫代酰基硅烷S-氧化物的立体特异性氟脱甲硅烷基化获得，同时保留构型。对脱硅反应机理以及酸和氟离子诱导的Z/E互变进行了详细的研究
Aromatic and aliphatic, not enethiolizable, thioaldehyde S-oxides (monosubstituted sulfines) are obtained from stereospecific fluorodesilylation of the corresponding thioacylsilane S-oxides with retention of configuration. A detailed investigation on the mechanism of the desilylation, as well as of the acid and fluoride ion induced Z/E interconversion has been performed