New ruthenium porphyrin polymeric membranes : preparation, characterization and catalytic activity in alkenes aziridination

New ruthenium porphyrin polymeric membranes : preparation, characterization and catalytic activity in alkenes aziridination
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新型钌卟啉聚合物膜:制备、表征及其在烯烃氮丙啶化中的催化活性

DOI:
10.1016/j.desal.2006.03.162
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发表时间:
2006
期刊:
影响因子:
9.9
通讯作者:
E. Drioli
E. Drioli
中科院分区:
工程技术2区
文献类型:
--
作者:
M. Buonomenna;E. Gallo;F. Ragaini;S. Cenini;E. Drioli

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近年来,催化领域新材料的研究引起了科学界的关注,以制备更加稳定、选择性好、易于回收和循环利用的催化剂。在这项工作中,我们研究了基于 PVDF 和 PDMS 聚合物的新型催化聚合物膜的制备和表征,该膜捕获了一系列钌卟啉。研究了它们作为烯烃氮丙啶化催化剂的行为。
In recent years the study of new materials in the field of catalysis has been attracted the attention of scientific world in order to prepare catalysts more stable, selective and with the possibility of their easy recovery and recycle. In this work we investigated the preparation and characterization of new catalytic polymeric membranes based on PVDF and PDMS polymers, entrapping a series of ruthenium porphyrin. Their behaviour as catalysts for olefins aziridination was studied.