Kinetic characterization of photoinduced anisotropy in diarylethene film

Kinetic characterization of photoinduced anisotropy in diarylethene film
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二芳基乙烯薄膜光致各向异性的动力学表征

DOI:
10.1016/j.optcom.2008.10.050
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发表时间:
2009-02
影响因子:
2.4
通讯作者:
Wang, Yingli
Wang, Yingli
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Chen, Liju;Yao, Baoli;Gao, Peng;Chen, Yi;Han, Junhe;Lei, Ming;Wang, Yingli

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基于我们提出的理论模型,对二芳基乙烯薄膜的光致各向异性动力学进行了全面的研究。计算了分子浓度、光致二向色性和双折射的动力学曲线。结果表明,随着激发曝光量的增加,着色分子浓度逐渐降低,直至饱和,光致各向异性先增大到最大值后逐渐减小。最佳曝光量为260 J/cm ~ 2。此外,还通过实验测量了探测光的透射率反映了各向异性。理论计算结果与实验数据进行了比较,两者基本一致。
Based on the theoretical model we have proposed, a complete study on the kinetics of photoinduced anisotropy in diarylethene films is performed. The kinetic curves of molecular concentration, photoinduced dichroism and birefringence are calculated, respectively. It is found that the colored molecular concentration decreases with the increase of the excitation exposure until saturation, and the photoinduced anisotropy increases to a maximum and then decreases gradually. The optimal exposure is 260J/cm2. In addition, the transmittance of probe beam reflecting the anisotropy is measured by experiment. The theoretical results are compared with experimental data, and basic concordance is found between both sets of data.
DOI: 10.1063/1.1688456
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影响因子: 4
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