A cooperative effect between support and the heterogenised metalloporphyrins on electrocatalytic oxygen reduction

A cooperative effect between support and the heterogenised metalloporphyrins on electrocatalytic oxygen reduction
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DOI:
10.1007/s10562-004-3756-7
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发表时间:
2005-05-01
期刊:
影响因子:
2.8
通讯作者:
Sánchez, F
Sánchez, F
中科院分区:
化学4区
文献类型:
--
作者:
Fuerte, A;Corma, A;Sánchez, F

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一种在二氧化硅、介孔MCM-41和分层沸石ITQ-2和ITQ-6上均相化卟啉和不同金属卟啉(Co,Fe)的新的通用方法,可以得到稳定的材料,作为电化学氧还原的活性催化剂,而不需要从电极上脱附催化剂。
A new general method to heterogenise porphyrins and different metalloporphyrins (Co, Fe) on silica, mesoporous MCM-41 and delaminated zeolites ITQ-2 and ITQ-6 yields stable materials, which act as active catalysts for the electrochemical oxygen reduction, without catalyst desorption from the electrode.