A balance between catalysis and nanoconfinement towards enhanced hydrogen storage performance of NaAlH4
A balance between catalysis and nanoconfinement towards enhanced hydrogen storage performance of NaAlH4
复制标题
催化和纳米限制之间的平衡以增强 NaAlH4 的储氢性能
DOI：
10.1016/j.jmst.2020.11.052
复制
发表时间：
2021-01-03
影响因子：
10.9
通讯作者：
Yu, Xuebin
中科院分区：
文献类型：
--
作者：
Chen, Wei;You, Lei;Yu, Xuebin
Owing to its favorable thermodynamics and high density, NaAlH4 has been widely regarded as a potential hydrogen storage material, but its practical application is hindered by the sluggish kinetics, high operating temperature and poor cycling stability. Here, taking advantage of Co-doped nanoporous carbon scaffolds as structural host, we develop a new strategy to balance the synergistic effect between the catalytic role of Co nanoparticles and the nanoconfinement role of porous carbon scaffolds via the controllable etching of Co nanoparticles towards enhanced hydrogen storage performance of NaAlH4. The etching of Co nanoparticles creates extra void spaces nearby catalytically active Co nanoparticles, which not only exerts the catalytic effect of Co nanoparticles, but also improves the nanoconfinement role in maintaining the cycling stability towards increased loading ratio and hence high systematic capacity. Induced by this balanced synergistic effect, the peak temperature for the dehydrogenation of NaAlH4 could be reduced to 164 degrees C, 97 degrees C lower than the bulk counterpart, even under an ultrahigh loading ratio of 67 %, and more importantly, the reversible systematic hydrogen storage capacity could still reach 3.3 wt.% after 5 cycles. This work opens up a new avenue to improve the hydrogen storage performance of various complex hydrides. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
