MONO- AND BIS-(2,2-BIPYRIDINE) AND (1,10-PHENANTHROLINE) CHELATES OF RUTHENIUM AND OSMIUM .1. MONOCHELATES OF BIVALENT, TERVALENT, AND QUADRIVALENT RUTHENIUM
MONO- AND BIS-(2,2-BIPYRIDINE) AND (1,10-PHENANTHROLINE) CHELATES OF RUTHENIUM AND OSMIUM .1. MONOCHELATES OF BIVALENT, TERVALENT, AND QUADRIVALENT RUTHENIUM
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DOI：
10.1071/ch9630042
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发表时间：
1963-01-01
影响因子：
1.1
通讯作者：
GYARFAS, EC
中科院分区：
文献类型：
--
作者：
DWYER, FP;GOODWIN, HA;GYARFAS, EC
单（菲咯啉）和单（联吡啶）钌（III）配合物已通过碱的盐酸盐与五氯水合钌（III）酸钾水溶液在25°C下反应制备，此时四氯菲咯啉钌（III）酸盐和四氯联吡啶钌（III）酸盐阴离子的不溶性菲咯啉和联吡啶盐BH[RuBCl 4]几乎定量分离。阳离子的消除可以通过氧化为四氯菲咯啉钌（IV）或四氯联吡啶钌（IV）来实现。后者的中性络合物然后可以被还原以产生酸H[RuBCl 4]或碱金属盐。螯合碱被牢固地结合在这些络合物中，但氯原子可被各种配体如水、吡啶或乙酰丙酮连续置换。
Mono(phenanthro1ine) and mono(bipyridine)ruthenium(III) complexes have been prepared by the reaction at 25°C between the hydrochlorides of the bases and aqueous potassium pentachloroaquoruthenate(III), when the insoluble phenanthrolinium and bipyridinium salts of the tetrachlorophenanthrolineruthenate(III) and tetrachlorobipyridineruthenate(III) anions, BH[RuBCl4], separated almost quantitatively. Elimination of the cation could be effected by oxidation to tetra-chlorophenanthrolineruthenium(IV) or tetrachlorobipyridineruthenium(IV). The latter neutral complexes could then be reduced to yield the acids H[RuBCl4] or alkali metal salts. The chelating base is firmly bound in these complexes but the chlorine atoms are replaceable successively by a wide variety of ligands such as water, pyridine, or acetylacetone.