Theories of relaxation

Theories of relaxation
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DOI:
10.1016/0022-3093(90)90775-h
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发表时间:
1990-08
影响因子:
3.5
通讯作者:
G. Scherer
G. Scherer
中科院分区:
材料科学2区
文献类型:
--
作者:
G. Scherer

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简要回顾了玻璃化转变的现象学。讨论了四类相变理论:解释粘度和/或松弛时间τp与温度的关系的流变学理论;预测松弛函数Mp形式的动力学理论;解释Mp形式和τp与温度关系的松弛理论;以及不参考微观模型描述松弛动力学的唯象理论。
The phenomenology of the glass transition is briefly reviewed. Four classes of theories for the transition are discussed:rheologicaltheories that account for the temperature dependence of the viscosity and/or relaxation timeτp;kinetictheories that predict the form of the relaxation functionMp;relaxationtheories that explain both the form ofMpand the temperature dependence ofτp; andphenomenologicaltheories that describe the kinetics of relaxation without reference to a microscopic model.