Reversal Circularly Polarized Luminescence of AIE-Active Chiral Binaphthyl Molecules from Solution to Aggregation
Reversal Circularly Polarized Luminescence of AIE-Active Chiral Binaphthyl Molecules from Solution to Aggregation
复制标题
AIE 活性手性联萘分子从溶液到聚集的反转圆偏振发光
DOI：
10.1002/chem.201502193
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发表时间：
2015-09-14
影响因子：
4.3
通讯作者：
Cheng, Yixiang
中科院分区：
文献类型：
--
作者：
Sheng, Yuan;Shen, Dong;Cheng, Yixiang
Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures.
