P-chiral phosphinoselenoic chlorides and optically active p-chiral phosphinoselenoic amides:: Synthesis and stereospecific interconversion with extrusion and addition reactions of the selenium atom
P-chiral phosphinoselenoic chlorides and optically active p-chiral phosphinoselenoic amides:: Synthesis and stereospecific interconversion with extrusion and addition reactions of the selenium atom
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DOI：
10.1246/cl.2004.878
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发表时间：
2004-07-05
影响因子：
1.6
通讯作者：
Murai, T
中科院分区：
文献类型：
--
作者：
Kimura, T;Murai, T
成功地合成了p -手性膦酸硒氯化物和首个具有旋光性的p -手性膦酸硒酰胺。此外，还研究了旋光性膦酸硒酰胺中硒原子挤出的立体定向相互转化以及旋光性氨基膦中硒原子的加入。
An efficient synthesis of P-chiral phosphinoselenoic chlorides and the first optically active P-chiral phosphinoselenoic amides was successfully achieved. Stereospecific interconversion with the extrusion of selenium atom from optically active phosphinoselenoic amides and the addition of selenium atom to optically active aminophosphines were also investigated.