Aminotriazines as locking fragments in macrocyclic synthesis
Aminotriazines as locking fragments in macrocyclic synthesis
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DOI：
10.1021/ic980243g
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发表时间：
1998-08-24
影响因子：
4.6
通讯作者：
Hayes, EJ
中科院分区：
文献类型：
--
作者：
Bernhardt, PV;Hayes, EJ
大环化合物（6-（4 '，6'-diamino-1 '，3'，5 '-triazinyl）-1，4，6，8，11-pentaazacyclotetradecane）copper（II）triperchlorate dihydrate，[Cu（HL 2）]（ClO 4）（3）。2H（2）O，（6-（6'-amino-4'-oxo-1'H-1'，3'，5'-triazinyl）-1，4，6，8，11-pentaazacyclotetradecane）copper（II）diperchlorate hydrate，[CuL3]（ClO4）（2）. H_2O和[（6-（4 ′，6 ′-二氧代-1 'H-1'，3 ′，5 ′-三嗪基）1，4，6，8，11-五氮杂环十四烷）铜（Ⅱ）]二高氯酸盐[CuL_4]（ClO_4）（2）的合成。合成的大环分别含有三聚氰胺、三聚氰酸二酰胺和三聚氰酸一酰胺环。[Cu（HL_2）]（ClO_4）（3）的X射线衍射分析。2 H（2）O，三斜晶系，空间群P（1），棒上，a = 9.489（10）埃，B = 12.340（2）埃，c = 24.496（4）埃，α = 87.74（10）度，β = 85.51（10）度，γ = 70.95（10）度，Z = 4，{[CuL 3]（ClO 4）（2）。H2O}2，单斜晶系，空间群C2/c，a = 18.624（8）埃，B = 17.160（2）埃，c = 15.998（6）埃，β = 117.82（2）度，Z = 4. [Cu（HL_2）]（ClO_4）（3）的结构。2 H（2）O显示了线性带的形成，由氢键和π-π堆积相互作用的组合形成。[CuL_3]（ClO_4）（2）的结构。H2O显示二聚体的形成，通过一个分子中的氧与另一个分子中的铜原子的配位键形成。已经确定了三聚氰酸二酰胺和三聚氰酸一酰胺部分的互变异构形式。这些化合物作为共结晶亚基的潜力进行了研究。
The macrocyclic compounds (6-(4',6'-diamino-1',3',5'-triazinyl)-1,4,6,8,11-pentaazacyclotetradecane)copper(II) triperchlorate dihydrate, [Cu(HL2)](ClO4)(3). 2H(2)O, (6-(6'-amino-4'-oxo-1'H-1',3',5'-triazinyl)-1,4,6,8,11-pentaazacyclotetradecane)copper(II) diperchlorate hydrate, [CuL3](ClO4)(2). H2O, and [(6-(4',6'-dioxo-1'H-1',3',5'-triazinyl) 1,4,6,8,11-pentaazacyclotetradecane)copper(II)] diperchlorate, [CuL4](ClO4)(2), have been synthesized. The macrocycles synthesized contain respectively pendant melamine, ammeline,and ammelide rings. The X-ray cyrstallographic analyses of [Cu(HL2)](ClO4)(3). 2H(2)O, triclinic, space group P (1) over bar, a = 9.489(10) Angstrom, b = 12.340(2) Angstrom, c = 24.496(4) Angstrom, alpha = 87.74(10)degrees beta = 85.51(10)degrees gamma = 70.95(10)degrees and Z = 4, and {[CuL3](ClO4)(2). H2O}2, monoclinic, space group C2/c, a = 18.624(8) Angstrom, b = 17.160(2) Angstrom, c = 15.998(6) Angstrom, beta = 117.82(2)degrees, and Z = 4, are reported. The structure of [Cu(HL2)](ClO4)(3). 2H(2)O shows the formation of linear tapes, formed by a combination of hydrogen bonds and pi-pi stacking interactions. The structure of [CuL3](ClO4)(2). H2O displays formation of dimers, formed by a coordinate bond from the oxygen in one molecule to the copper atom of another. The tautomeric forms of the ammeline and ammelide moieties have been determined. The potential of these compounds as subunits for cocrystallization has been investigated.