Pincer-Supported Carbonyl Complexes of Cobalt(I)
Pincer-Supported Carbonyl Complexes of Cobalt(I)
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DOI：
10.1021/acs.organomet.7b00434
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发表时间：
2017-08-28
期刊：
影响因子：
2.8
通讯作者：
Heinekey, D. Michael
中科院分区：
文献类型：
--
作者：
Guard, Louise M.;Hebden, Travis J.;Heinekey, D. Michael
一对POCOP支撑的单和二羰基钴配合物已被制备和晶体学表征。（（POCOP）-P-tBu）Co（CO）与H-2、酸和一氧化碳的反应性已与先前报道的Rh和Ir对应物进行了比较。Co被发现与Rh和Ir共享反应特性。
A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of ((POCOP)-P-tBu)Co(CO) with H-2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir.