MICROBIOLOGICAL TRANSFORMATIONS .28. ENANTIOCOMPLEMENTARY EPOXIDE HYDROLYZES AS A PREPARATIVE ACCESS TO BOTH ENANTIOMERS OF STYRENE OXIDE
MICROBIOLOGICAL TRANSFORMATIONS .28. ENANTIOCOMPLEMENTARY EPOXIDE HYDROLYZES AS A PREPARATIVE ACCESS TO BOTH ENANTIOMERS OF STYRENE OXIDE
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DOI：
10.1021/jo00072a044
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发表时间：
1993-09-24
影响因子：
3.6
通讯作者：
FURSTOSS, R
中科院分区：
文献类型：
--
作者：
PEDRAGOSAMOREAU, S;ARCHELAS, A;FURSTOSS, R
初步研究在分析规模上进行，将roc-1 （1 g/L）与真菌a . niger的缓冲休止细胞悬浮液孵育。不同孵育时间后1的消失情况如图1和方案1所示。这些结果表明，首先，在这些条件下，1发生了快速水解。
Preliminary studies were performed on an analytical scale by incubating roc-1 (1 g/L) with a buffered resting-cell suspension of the fungus A. niger. The disappearance of 1, after different incubationperiods, is shown in Figure 1 and Scheme I. These results show, first, that rapid hydrolysis of 1 occurs under these conditions® and, second,