Linear and star-shaped naphthalimide-fused pyrazinacenes.
Linear and star-shaped naphthalimide-fused pyrazinacenes.
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DOI：
10.1039/c2cc36791b
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发表时间：
2013-01
影响因子：
4.9
通讯作者：
Helena Herrera;P. de Echegaray;M. Urdanpilleta;M. J. Mancheño;E. Mena‐Osteritz;P. Bäuerle;J. Segura
中科院分区：
文献类型：
--
作者：
Helena Herrera;P. de Echegaray;M. Urdanpilleta;M. J. Mancheño;E. Mena‐Osteritz;P. Bäuerle;J. Segura
合成了一种具有二酮官能团的新型萘酰亚胺衍生物，并将其用于开发一类高度对称的、平坦的、n型半导体萘酰亚胺基吡嗪并苯。通过改变这些化合物的对称性和萘酰亚胺组分的数量，实现了它们的电化学、生物物理学和形态学性质的微调。
A novel naphthalimide derivative endowed with a diketone functionality has been synthesized and used to develop a family of highly symmetric, flat, n-type semiconducting naphthalimide-based pyrazinacenes. By changing the symmetry of these compounds and the number of naphthalimide constituents, fine tuning of their electrochemical, photophysical, and morphological properties is achieved.