An Ir3L2 complex with anion binding pockets: photocatalytic E-Z isomerization via molecular recognition
An Ir3L2 complex with anion binding pockets: photocatalytic E-Z isomerization via molecular recognition
复制标题
具有阴离子结合袋的 Ir3L2 复合物：通过分子识别进行光催化 E-Z 异构化
DOI：
10.1039/d1cc03620c
复制
发表时间：
2021
影响因子：
4.9
通讯作者：
H. Takezawa and M. Fujita
中科院分区：
文献类型：
--
作者：
H. Sunohara. K. Koyamada;H. Takezawa and M. Fujita
具有光敏中心的分子主体根据其分子识别能力提供光响应主客体特性。在这里，我们构建了一种自组装的光活性 Ir(iii) 笼形复合物，其边缘含有阴离子结合袋。该复合物的阴离子识别能力能够有效催化可见光诱导的阴离子苯乙烯衍生物的 E-Z 异构化。
A molecular host with photosensitizing centers provides photo-responsive host–guest properties based on its molecular recognition ability. Here, we construct a self-assembled photoactive Ir(iii) cage-shaped complex that contains anion binding pockets on its rim. The anion recognition ability of the complex enables efficient catalysis of the visible-light-induced E–Z isomerization of an anionic styrene derivative.