Yttrium bisphosphonate STA-13: a racemic phosphonate metal organic framework with permanent microporosity.

Yttrium bisphosphonate STA-13: a racemic phosphonate metal organic framework with permanent microporosity.
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DOI:
10.1039/c0dt00233j
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发表时间:
2010-07
影响因子:
4
通讯作者:
M. Wharmby;Stuart R. Miller;J. Groves;I. Margiolaki;S. Ashbrook;P. Wright
M. Wharmby;Stuart R. Miller;J. Groves;I. Margiolaki;S. Ashbrook;P. Wright
中科院分区:
化学2区
文献类型:
--
作者:
M. Wharmby;Stuart R. Miller;J. Groves;I. Margiolaki;S. Ashbrook;P. Wright

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钇和其他类似半径的三价金属阳离子与外消旋N,N '-2-甲基哌嗪双(亚甲基膦酸)的结晶得到显示配位和氢键以及永久孔隙的小孔双膦酸盐金属-有机骨架固体。
Crystallisation of yttrium and other trivalent metal cations of similar radius with racemic N,N'-2-methylpiperazinebis(methylene phosphonic acid) gives a small pore bisphosphonate metal-organic framework solid displaying coordinative and hydrogen bonding and permanent porosity.