Mesoporous carbon supported nickel phosphide catalysts prepared by solid phase reaction

Mesoporous carbon supported nickel phosphide catalysts prepared by solid phase reaction
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固相反应制备介孔碳负载磷化镍催化剂

DOI:
10.1016/j.catcom.2009.05.009
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发表时间:
2009-07
影响因子:
3.7
通讯作者:
沈俭一
沈俭一
中科院分区:
化学3区
文献类型:
--
作者:
沈俭一

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在473 K时,Ni阳离子与次磷酸根在介孔炭(MC)的孔内发生固相反应,生成了高度分散的Ni 2 P。结果表明,该催化剂对二苯并噻吩(DBT)的加氢脱硫(HDS)和喹啉的加氢脱氮(HDN)活性均高于高温还原磷酸盐制备的Ni 2 P/SiO2催化剂。
The solid phase reaction between nickel cations and hypophosphites might occur at 473K in the pores of mesoporous carbon (MC), resulting in the highly dispersed Ni2P on the surface of the MC support. The Ni2P/MC catalysts thus prepared exhibit higher activities for the hydrodesulfurization (HDS) of dibenzothiophene (DBT) and the hydrodenitrogenation (HDN) of quinoline than the Ni2P/SiO2catalysts prepared by the reduction of phosphate at high temperatures.
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