Efficient Barbier reaction of carbonyl compounds improved by a phase transfer catalyst in waterElectronic supplementary information (ESI) available: experimental procedure for allylation and spectral data for the allylation products. See http://www.rsc.org./suppdata/gc/b2/b206452a/
Efficient Barbier reaction of carbonyl compounds improved by a phase transfer catalyst in waterElectronic supplementary information (ESI) available: experimental procedure for allylation and spectral data for the allylation products. See http://www.rsc.org./suppdata/gc/b2/b206452a/
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DOI：
10.1039/b206452a
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发表时间：
2002-12
期刊：
影响因子：
9.8
通讯作者：
Zhenggen Zha;Yusong Wang;Guang Yang;Li Zhang;Zhiyong Wang
中科院分区：
文献类型：
--
作者：
Zhenggen Zha;Yusong Wang;Guang Yang;Li Zhang;Zhiyong Wang
采用相转移催化剂(PTC)催化锡催化的烯丙化反应。这种原子经济的反应是在室温下在水中进行的，没有任何辅助。此外，还研究了PTC对烯丙化反应非对映选择性的影响。
A phase transfer catalyst (PTC) is employed in allylation mediated by tin. This atom economical reaction was performed in water at room temperature without any assistance. In addition, the influence of PTC on diastereoselectivity of the allylation was studied.