Synthesis and Lithium Fast-Ion Conductivity of a New Complex Hydride Li3(NH2)2I with Double-Layered Structure
Synthesis and Lithium Fast-Ion Conductivity of a New Complex Hydride Li3(NH2)2I with Double-Layered Structure
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DOI：
10.1021/cm1006857
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发表时间：
2010-04
影响因子：
8.6
通讯作者：
M. Matsuo;Toyoto Sato;Y. Miura;H. Oguchi;Yu Zhou;H. Maekawa;H. Takamura;S. Orimo
中科院分区：
文献类型：
--
作者：
M. Matsuo;Toyoto Sato;Y. Miura;H. Oguchi;Yu Zhou;H. Maekawa;H. Takamura;S. Orimo
报道了具有快速离子传导特性的新型络合氢化物Li3(NH2)2I。Li3(NH2)2I具有典型的双层结构，a = 7.09109(5) a, c = 11.50958(10) a （P63mc）。由于独特的晶体结构，Li3(NH2)2I在296 K下表现出1 × 10−5 S/cm的快速离子电导率。
The new complex hydride Li3(NH2)2I exhibiting fast-ion conduction is reported. Li3(NH2)2I has the characteristic double-layered structure with a = 7.09109(5) A and c = 11.50958(10) A (P63mc). Because of the unique crystal structure, Li3(NH2)2I exhibits fast-ion conductivity of 1 × 10−5 S/cm at 296 K.