CORANNULENE TETRAANION - A NOVEL SPECIES WITH CONCENTRIC ANIONIC RINGS

CORANNULENE TETRAANION - A NOVEL SPECIES WITH CONCENTRIC ANIONIC RINGS
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DOI:
10.1002/anie.199216361
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发表时间:
1992-12-01
期刊:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
影响因子:
--
通讯作者:
SCOTT, LT
SCOTT, LT
中科院分区:
其他
文献类型:
--
作者:
AYALON, A;RABINOVITZ, M;SCOTT, LT

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corannulene(1)的四阴离子2被描述为轮烯内轮烯,通过在-78 ℃下用锂还原1制备,然后通过NMR光谱进行研究。具有同心芳环的化合物一直在寻找。
Described as an annulene-within-an-annulene, the tetraanion 2 of corannulene (1) was prepared by reducing 1 with lithium at -78-degrees-C and then investigated by NMR spectroscopy. Compounds with concentric aromatic rings have long been sought.