Evidence for a lowest energy 3 MLCT excited state in [Fe(tpy)(CN) 3 ] −
Evidence for a lowest energy 3 MLCT excited state in [Fe(tpy)(CN) 3 ] −
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[Fe(tpy)(CN) 3 ] 中存在最低能量 3 MLCT 激发态的证据 —
DOI：
10.1039/d1cc01090e
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发表时间：
2021
影响因子：
4.9
通讯作者：
Rack, Jeffrey J.
中科院分区：
文献类型：
--
作者：
Vittardi, Sebastian B.;Magar, Rajani Thapa;Schrage, Briana R.;Ziegler, Christopher J.;Jakubikova, Elena;Rack, Jeffrey J.
[FeII(tpy)(CN)3]−的瞬态吸收数据显示了具有~ 10 ps动力学成分的3MLCT的光谱特征。这些数据得到了DFT和TD-DFT计算的支持，表明激发态排序对配合物上氰化物配体的数量有响应。
Transient absorption data of [FeII(tpy)(CN)3]− reveals spectroscopic signatures indicative of 3MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex.