A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic estersElectronic supplementary information (RSI) available: experimental procedures for a detailed preparation of complex 4 and cross-coupling experiments. S
A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic estersElectronic supplementary information (RSI) available: experimental procedures for a detailed preparation of complex 4 and cross-coupling experiments. S
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σ4, λ5-膦钯配合物：一种新型磷配体和催化剂在 Pd 催化形成芳基硼酸酯中的应用电子补充信息 (RSI) 可用：配合物 4 的详细制备和交叉偶联实验的实验程序。 S
DOI：
10.1039/b203550b
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发表时间：
2002
影响因子：
4.9
通讯作者：
P. Floch
中科院分区：
文献类型：
--
作者：
M. Doux;N. Mézailles;M. Melaimi;L. Ricard;P. Floch
具有金属化叶立德P-原子的S-P-S钳形配体的钯（II）络合物有效地催化频哪醇硼烷和各种碘代芳基之间的偶联，以产生相应的芳基硼酸酯（TON在5100和76500之间）。
A palladium(II) complex of a S–P–S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76500).