In-Water Truly Monodisperse Aggregation of Gear-Shaped Amphiphiles Based on Hydrophobic Surface Engineering
In-Water Truly Monodisperse Aggregation of Gear-Shaped Amphiphiles Based on Hydrophobic Surface Engineering
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DOI：
10.1021/ja1069135
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发表时间：
2010-09-29
影响因子：
15
通讯作者：
Shionoya, Mitsuhiko
中科院分区：
文献类型：
--
作者：
Hiraoka, Shuichi;Nakamura, Takashi;Shionoya, Mitsuhiko
正好有六个齿轮状的两亲分子自组装成一个高度稳定的、水溶性的盒状胶囊，其中组件的锯齿状疏水表面像齿轮一样相互啮合。一个水溶性的四面体形状的胶囊也被构建从四个齿轮状的两亲分子与模板客人。这些研究结果提供了一个指导方针，创建一个给定数量的两亲物的基础上疏水表面工程的聚集体。
Exactly six gear-shaped amphiphiles self-assemble into a highly stable, water-soluble, box-shaped capsule, in which indented hydrophobic surfaces of the components mesh with each other like gears. A water-soluble, tetrahedron-shaped capsule was also constructed from four gear-shaped amphiphiles with a template guest. These findings provide a guideline for creating aggregates with a given number of amphiphiles based on hydrophobic surface engineering.