Structure determination of SnZrS3

Structure determination of SnZrS3
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SnZrS3的结构测定

DOI:
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发表时间:
1993
期刊:
影响因子:
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通讯作者:
J. Boer
J. Boer
中科院分区:
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文献类型:
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作者:
A. Meetsma;G. Wiegers;J. Boer

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锡锆三硫化物的结构是NH_4CdCl_3型,具有双列共边Zr八面体。这些柱通过Sn原子连接在一起。Sn与三个S原子配位,位置为2 × 2.619(2)和2.765(2)埃;第四个S原子位于3.065(2)埃。锆的配位近似为八面体,具有6个S原子,在2.524(2)、2 × 2.545(2)、2.582(2)和2 × 2.592(2)埃。还收集了粉末衍射数据;硫化锡锆的JCPDS芸香编号为44-1494。
The structure of tin zirconium trisulfide is of the NH4CdCl3 type with double columns of edge-sharing Zr octahedra. These columns are linked together by Sn atoms. Sn is coordinated to three S atoms at 2 x 2.619 (2) and 2.765 (2) angstrom; a fourth S atom is at 3.065 (2) angstrom. The zirconium coordination is approximately octahedral with six S atoms at 2.524 (2), 2 x 2.545 (2), 2.582 (2) and 2 x 2.592 (2) angstrom. Powder diffraction data were also collected; the JCPDS rue No. for tin zirconium sulfide is 44-1494.