Photocatalytic C-C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex
Photocatalytic C-C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex
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DOI：
10.1002/anie.201609035
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发表时间：
2016-12-05
影响因子：
16.6
通讯作者：
Zuo, Zhiwei
中科院分区：
文献类型：
--
作者：
Guo, Jing-Jing;Hu, Anhua;Zuo, Zhiwei
利用氯化铈(III)络合物通过可见光诱导的光氧化还原催化实现了环烷醇C-C键的裂解和胺化的一般策略。这种操作简单的方法已成功应用于多种未拉紧环醇，并且代表了催化C-C键断裂和未拉紧仲环烷醇官能化的第一个例子。
A general strategy for the cleavage and amination of C-C bonds of cycloalkanols has been achieved through visible-light-induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C-C bond cleavage and functionalization of unstrained secondary cycloalkanols.