The Structure of Aqueous Non-electrolyte Solutions (Comparative Analysis of the Thermodynamic Properties of Aqueous and Non-aqueous Binary Systems)
The Structure of Aqueous Non-electrolyte Solutions (Comparative Analysis of the Thermodynamic Properties of Aqueous and Non-aqueous Binary Systems)
复制标题
非电解质水溶液的结构（水和非水二元体系热力学性质的比较分析）
DOI：
--
复制
发表时间：
1971
期刊：
影响因子：
--
通讯作者：
V. A. Rogov
中科院分区：
文献类型：
--
作者：
Yu. l. Naberukhin;V. A. Rogov
大量的水和醇二元体系的热力学性质的比较已经确定，以下性质仅是水溶液的特征：（1）在低非电解质浓度下的负混合熵和负混合熵;（2）在中等浓度下的负偏摩尔熵和负混合熵。第一个属性是当空位被填充时水结构稳定的证据。第二个意味着该解决方案具有微观异质结构，由于在它的有序区域（小球）的存在。讨论了球的性质及其合作性质的问题。参考文献包括49篇参考文献。
A comparison of the thermodynamic properties of a large number of aqueous and alcoholic binary systems has established that the following properties are characteristic only of aqueous solutions: (1) negative enthalpies and entropies of mixing at low non-electrolyte concentrations; (2) negative partial molar entropies and enthalpies of water at moderate concentrations. The first property is evidence of the stabilisation of the water structure when the vacancies are filled. The second implies that the solution has a microheterogeneous structure owing to the presence in it of ordered regions (globules). The problem of the nature of the globules and their cooperative properties is discussed. The bibliography includes 49 references.