Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol
Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol
复制标题
DOI：
10.1039/c4cc09471a
复制
发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Nielsen, M.
中科院分区：
文献类型：
--
作者：
Alberico, E.;Nielsen, M.
实现含水甲醇彻底脱氢为氢气和CO2以及逆反应（CO2氢化为甲醇和水）的可能性可以为基于甲醇的经济铺平道路，作为有前途的可再生能源系统的一部分。最近，均相催化体系已被报道，它能够在温和的条件下促进这两个反应中的一个或另一个。在这里，我们回顾和讨论这些发展。
The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.