Quantization of the highest levels in a molecular potential
Quantization of the highest levels in a molecular potential
复制标题
分子势最高水平的量化
DOI：
10.1209/epl/i1998-00155-0
复制
发表时间：
1998
期刊：
影响因子：
1.8
通讯作者：
J. Vigué
中科院分区：
文献类型：
--
作者：
C. Boisseau;É. Audouard;J. Vigué
通常的JWKB量子化公式不能很好地描述分子势中最高能级的位置。这是由于连续态的量子阈值行为的束缚态的镜像效应。这一新的影响在本信中进行了描述，并简要讨论了一些后果。特别是，我们讨论了最高振动能级的结合能的概率分布，并表明它的形状被强烈修改。
The position of the highest level in a molecular potential is not well described by the usual JWKB quantization formula. This is due to an effect which is the mirror image for bound states of the quantum threshold behaviour for the continuum states. This new effect is described in the present letter and some consequences are briefly discussed. In particular, we discuss the probability distribution of the binding energy of the highest vibrational level and show that its shape is strongly modified.