Ring-retentive deprotonation of cyclopropene-3-carboxamides
Ring-retentive deprotonation of cyclopropene-3-carboxamides
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DOI：
10.1016/j.tet.2010.04.123
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发表时间：
2010-07-03
期刊：
影响因子：
2.1
通讯作者：
Rubin, Michael
中科院分区：
文献类型：
--
作者：
Kim, Ryan;Sherrill, William M.;Rubin, Michael
A remarkable stability of anionic species generated from cyclopropene-3-carboxamides toward ring-opening is demonstrated. The resulting cyclopropenyllithium species can be reacted with a range of electrophiles, which allows for efficient introduction of additional substituents at C1 of the strained ring. (C) 2010 Elsevier Ltd. All rights reserved.
