REDUCED [FE8S6] CLUSTERS - BINDING LINKS BETWEEN FES AND ACTIVE-CENTERS OF IRON-SULFUR PROTEINS
REDUCED [FE8S6] CLUSTERS - BINDING LINKS BETWEEN FES AND ACTIVE-CENTERS OF IRON-SULFUR PROTEINS
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DOI：
10.1002/anie.199308631
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发表时间：
1993-06-01
期刊：
影响因子：
--
通讯作者：
OPITZ, U
中科院分区：
文献类型：
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作者：
POHL, S;OPITZ, U
以[Fe 4S 4]2+为原料，通过还原铁和除硫，合成了以前难以得到的[Fe 8 S6]4+簇合物（簇合物阴离子[Fe 8 S6 I8]4-（1））。这种类型的簇，它只包含Fe（II）中心，不仅是作为FeS反应的分子模型的兴趣，但也可能会经历进一步的反应，由于缺乏配体和金属的氧化态。
By the reduction of iron and removal of sulfur, the previously inaccessible [Fe8S6]4+ clusters (as cluster anion [Fe8S6I8]4- (1)) were synthesized from [Fe4S4]2+. This type of cluster, which contains exclusively Fe(II) centers, is not only of interest as a molecular model for reactions of FeS, but may also undergo further reaction on account of the lack of ligands and the oxidation state of the metal.