Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes
Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes
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DOI：
10.1016/j.tetlet.2004.10.168
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发表时间：
2005-01-03
影响因子：
1.8
通讯作者：
Hashimoto, S
中科院分区：
文献类型：
--
作者：
Nakajima, M;Kotani, S;Hashimoto, S
证明了手性氧化膦BINAPO作为烯丙基三氯硅烷与醛的对映选择性加成的催化剂的有效性，其中二异丙基乙胺和四丁基碘化铵作为添加剂的组合对于加速催化循环至关重要。(C)2004爱思唯尔有限公司保留所有权利。
The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantio elective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle. (C) 2004 Elsevier Ltd. All rights reserved.