Redox-Controlled Crotyl Alcohol Selective Oxidation: In Situ Oxidation and Reduction Dynamics of Catalytic Pd Nanoparticles via Synchronous XANES/MS
Redox-Controlled Crotyl Alcohol Selective Oxidation: In Situ Oxidation and Reduction Dynamics of Catalytic Pd Nanoparticles via Synchronous XANES/MS
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DOI：
10.1021/cs300445y
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发表时间：
2012-09
期刊：
影响因子：
12.9
通讯作者：
Christine V. Gaskell;Christopher M. A. Parlett;M. Newton;K. Wilson;A. Lee
中科院分区：
文献类型：
--
作者：
Christine V. Gaskell;Christopher M. A. Parlett;M. Newton;K. Wilson;A. Lee
原位同步MS/XANES研究表明，钯催化巴豆醇的选择性好氧氧化受氧化态和还原态平衡的调节。动态XANES测量提供了一种新的、快速的方法来确定纳米颗粒的氧化还原动力学，并确定重要参数以优化催化剂设计。
In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.