Decarboxylative allytations of ester enolate equivalents
Decarboxylative allytations of ester enolate equivalents
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DOI：
10.1039/c4ob01752h
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发表时间：
2014-11-14
影响因子：
3.2
通讯作者：
Tunge, Jon A.
中科院分区：
文献类型：
--
作者：
Ariyarathna, Yamuna;Tunge, Jon A.
各种酯烯酸等同物在原位生成，并通过钯催化脱羧烯化以高产量进行α -烯丙基化。在环境条件下，转化在很短的反应时间内完成。a-烯丙化酰基衍生物的合成可以通过酰基取代或还原得到其他羧酸和醇衍生物。
A variety of ester enolate equivalents are generated in situ and undergo alpha-allylation in high yields via palladium-catalyzed decarboxylative allylation. The transformations are complete within very short reaction times under ambient conditions. Synthesis of a-allylated acyl derivatives provides access to other carboxylic acid and alcohol derivatives via acyl group substitution or reduction.