Absorption Spectra of Colored Isomer of Diarylethene in Single Crystals

Absorption Spectra of Colored Isomer of Diarylethene in Single Crystals
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单晶中二芳基乙烯有色异构体的吸收光谱

DOI:
10.1246/cl.2002.1224
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发表时间:
2002
期刊:
影响因子:
1.6
通讯作者:
M. Irie
M. Irie
中科院分区:
化学4区
文献类型:
--
作者:
S. Kobatake;M. Morimoto;Y. Asano;A. Murakami;Shinichiro Nakamura;M. Irie

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在紫外线照射下,1,2-双(2,5-二甲基-3-噻吩基)全氟环戊烯晶体中产生的有色异构体在535nm处显示出最大吸收,这比己烷中的505nm长30nm。光谱位移归因于晶体中光生闭环异构体的应变结构。
The colored isomer produced in 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene crystal upon irradiation with ultraviolet light showed an absorption maximum at 535 nm, which is 30 nm longer than that in hexane, 505 nm. The spectral shift is ascribed to the strained structure of the photogenerated closed-ring isomer in the crystal.
DOI: 10.1021/ja983717j
发表时间: 1999-03-24
影响因子: 15
作者:
Kobatake, S;Yamada, T;Irie, M
通讯作者: Irie, M