New stable reagents for the nucleophilic trifluoromethylation. Part 2: Trifluoromethylation with silylated hemiaminals of trifluoroacetaldehyde
New stable reagents for the nucleophilic trifluoromethylation. Part 2: Trifluoromethylation with silylated hemiaminals of trifluoroacetaldehyde
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DOI：
10.1016/s0040-4039(00)01552-5
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发表时间：
2000-11-04
影响因子：
1.8
通讯作者：
Blond, G
中科院分区：
文献类型：
--
作者：
Billard, T;Langlois, BR;Blond, G
以含氟半缩酮为原料，合成了新的亲核三氟甲基化试剂。它们由不可烯醇化的羰基化合物提供甲硅烷基化的三氟甲基甲醇。(C)2000爱思唯尔科技有限公司版权所有。
New reagents for the nucleophilic trifluoromethylation have been easily synthesized from fluoral hemiketal. They provide silylated trifluoromethylcarbinol from non-enolizable carbonyl compounds. (C) 2000 Elsevier Science Ltd. All rights reserved.