Response to the comment on ‘‘Self‐nucleation in the sulfuric acid–water system’’
Response to the comment on ‘‘Self‐nucleation in the sulfuric acid–water system’’
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对“硫酸-水系统中的自成核”评论的回应
DOI：
10.1063/1.442202
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发表时间：
1981
期刊：
影响因子：
--
通讯作者：
G. J. Doyle
中科院分区：
文献类型：
--
作者：
G. J. Doyle
Renninger等人[J. Chem. Phys. 75，1584（1981）]批评Doyle在双组分液滴[J. Chem. Phys. 35，795（1961）]的自由能表面上寻找鞍点的技术的具体依据被驳斥。然而，这种技术的扩展，以修改开尔文和拉普拉斯的关系似乎是无效的Renninger等人认为。该技术的有效性可能仅限于毛细管成核理论的两个组件系统。
The specific basis for a criticism by Renninger et al. [J. Chem. Phys. 75, 1584 (1981)] of Doyle’s technique for finding the saddle point on the free energy surface of a two‐component liquid droplet [J. Chem. Phys. 35, 795 (1961)] is refuted. However, extensions of this technique to modify the Kelvin and Laplace relationships seems invalid as argued by Renninger et al. The technique’s validity is probably confined to capillary nucleation theory for a two component system.