Catalytic hydrogen production at cobalt centres
Catalytic hydrogen production at cobalt centres
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DOI：
10.1016/j.ccr.2010.06.004
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发表时间：
2010-11
影响因子：
20.6
通讯作者：
S. Losse;J. Vos;S. Rau
中科院分区：
文献类型：
--
作者：
S. Losse;J. Vos;S. Rau
讨论了各种钴配合物在质子还原反应中的催化性能。电催化以及光催化系统的解决，并允许不同的系统之间的比较报告相当注意的是支付给所使用的反应条件。对于光催化质子还原的钌，铱和钌络合物的范围内讨论作为潜在的光敏剂。详细讨论了光催化体系，并讨论了牺牲剂的性质和所用溶剂等问题。分子间和分子内的双链均被考虑。所取得的成果被认为是与可持续能源的发展需要。
The catalytic properties of a wide range of cobalt complexes with respect to proton reduction are discussed. Electrocatalytic as well as photocatalytic systems are addressed and to allow comparison between the different systems reported considerable attention is paid to the reaction conditions used. For the photocatalytic proton reduction a range of ruthenium, iridium and rhenium complexes are discussed as potential photosensitizers. The photocatalytic systems are discussed in detail and issues such as the nature of the sacrificial agent and the solvents used. Both intermolecular and intramolecular photocatalysis are considered. The results obtained are considered with respect to the need to the development of sustainable energy sources.