Structural Interconversion and Regulation of Optical Properties of Stable Hypercoordinate Dipyrrin-Silicon Complexes

Structural Interconversion and Regulation of Optical Properties of Stable Hypercoordinate Dipyrrin-Silicon Complexes
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DOI:
10.1021/ja2001924
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发表时间:
2011-04-06
影响因子:
15
通讯作者:
Nabeshima, Tatsuya
Nabeshima, Tatsuya
中科院分区:
化学1区
文献类型:
--
作者:
Sakamoto, Naoya;Ikeda, Chusaku;Nabeshima, Tatsuya

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新型五配位二吡咯啉硅配合物显示出有效的红色或近红外荧光,和硅烷醇和硅氧烷衍生物之间的结构相互转换导致的光学性质的显着变化。
Novel pentacoordinate dipyrrin-silicon complexes showed efficient red or near-IR fluorescence, and the structural interconversion between silanol and siloxane derivatives resulted in significant changes in the optical properties.