A multi-stimuli responsive ruthenium complex for catalytic water oxidation
A multi-stimuli responsive ruthenium complex for catalytic water oxidation
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DOI：
10.1039/d0cc04940a
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发表时间：
2020-10-28
影响因子：
4.9
通讯作者：
Umemura, Yasushi
中科院分区：
文献类型：
--
作者：
Hirahara, Masanari;Goto, Hiroki;Umemura, Yasushi
合成了一种具有多刺激响应性异构化反应的Ru配合物。该络合物对水氧化的催化活性表现出对可见光照射的响应和对光异构化和热反异构化的热响应。密度泛函理论计算表明，络合物中的侧链是控制催化活性的关键。
A ruthenium complex showing multi-stimuli-responsive isomerization was synthesized. The catalytic activity of this complex toward water oxidation showed responses to visible-light irradiation and heat due to photoisomerization and thermal back-isomerization, respectively. DFT calculations suggested that a pendant moiety in the complex was key to controlling the catalytic activity.