Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis.
Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis.
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DOI：
10.1039/b923918a
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发表时间：
2010-03
影响因子：
4.9
通讯作者：
N. Takahashi;Takeshi Ito;Yohei Matsuda;N. Kogure;M. Kitajima;H. Takayama
中科院分区：
文献类型：
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作者：
N. Takahashi;Takeshi Ito;Yohei Matsuda;N. Kogure;M. Kitajima;H. Takayama
三聚吲哚生物碱psychotrimine的首次不对称全合成是通过不对称Ireland-Claisen重排反应构建手性季碳中心，从而建立了psychotrimine的绝对构型。
The first asymmetric total synthesis of psychotrimine, a trimeric indole alkaloid, was accomplished via an asymmetric Ireland-Claisen rearrangement to construct a chiral quaternary carbon center, thereby establishing the absolute configuration of psychotrimine.