Low multielectron reduction potentials of emerald green [60]fullerenes
Low multielectron reduction potentials of emerald green [60]fullerenes
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DOI：
10.1246/cl.2006.762
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发表时间：
2006-07-05
影响因子：
1.6
通讯作者：
Chiang, Long Y.
中科院分区：
文献类型：
--
作者：
Canteenwala, Taizoon;Li, Wenguang;Chiang, Long Y.
十二乙基翡翠绿富勒烯(EFN)、C-60[-C(CH3)(CO2Et)(2)](6)或EF-6MC(2)的独特的双三苯互联全反式18-三轮烯电子构型，使富勒烯笼子保持与C-60相似的电子亲和力和高的多电子接受能力，E-1(红色)=-0.36V，E-2(红色)=-0.88V，E-3(红色)=-1.45V。
Unique double-triphenylene interconnected all-trans 18-trannulene electronic configuration of dodecaethylated emerald green fullerene (EFn), C-60[-C(CH3)(CO2Et)(2)](6) or EF-6MC(2), allows the fullerene cage to retain similar affinity for electrons as C-60 and high multielectron accepting capability with E-1(Red) = -0.36V, E-2(Red) = -0.88 V, and E-3(Red) = -1.45 V vs. Ag/AgCl.