Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions
Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions
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DOI：
10.1039/b504996b
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发表时间：
2005-01-01
影响因子：
4.9
通讯作者：
Vicic, DA
中科院分区：
文献类型：
--
作者：
Jones, GD;McFarland, C;Vicic, DA
使用tpy'（tpy' = 4，4 '，4”-三叔丁基三联吡啶）作为镍的配体允许分离Ni（I）-烷基络合物和Ni（II）-卤代烷络合物，这两者都可以用作烷基交叉偶联反应中关键步骤的机理探针。
The use of tpy' (tpy' = 4,4',4"-tri-tert-butyl-terpyridine) as a ligand for nickel allows for the isolation of a Ni(I)-alkyl complex and a Ni(II)-alkyl halide complex, both of which can be used as mechanistic probes of key steps in alkyl cross-coupling reactions.