Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate
Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate
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DOI：
10.1039/c1ce05211j
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发表时间：
2011-04
期刊：
影响因子：
3.1
通讯作者：
Yan-Li Miao;Jun‐Liang Liu;Ji-Dong Leng;Zhuo-jia Lin;M. Tong
中科院分区：
文献类型：
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作者：
Yan-Li Miao;Jun‐Liang Liu;Ji-Dong Leng;Zhuo-jia Lin;M. Tong
报道了两种独特的镝（III）配位化合物，它们具有由四个共享顶点的立方体状单元组成的类似十二核簇，[2Cl−∧{Dy12(OH)16(phenda)8(H2O)8}]2+。磁性研究表明，这两种化合物都表现出缓慢的磁弛豫。
Two unique dysprosium(III) coordination compounds with similar dodecanuclear clusters composed of four vertex-sharing cubane-like units, [2Cl− ⊂ {Dy12(OH)16(phenda)8(H2O)8}]2+, were reported. Magnetic studies reveal that both compounds exhibit slow magnetic relaxation.