Ba2PO4I, Sr2PO4I, and Pb2PO4I – A New Structure Type and Three of Its Representatives†
Ba2PO4I, Sr2PO4I, and Pb2PO4I – A New Structure Type and Three of Its Representatives†
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Ba2PO4I、Sr2PO4I 和 Pb2PO4I – 一种新结构类型及其三种代表 –
DOI:
10.1002/zaac.201400221
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发表时间:
2014
期刊:
影响因子:
--
通讯作者:
Guido Kickelbick
中科院分区:
文献类型:
--
作者:
Robert Haberkorn;Jessica Bauer;Guido Kickelbick
The compound Pb2PO4I was synthesized via a solid state reaction under inert conditions. None of the known structure types of other compounds of the typeM2(P,V,As,Cr)O4(F,Cl,Br,I) provided a similar pattern. Structure solution was carried out by evaluation of an X‐ray diffractogram of polycrystalline powder using the methods simulated annealing and difference Fourier. Pb2PO4I crystallizes in the space groupP21/cwith the lattice parametersa= 9.0451(1) Å,b= 8.7593(1) Å,c= 8.5740(1) Å, andβ= 111.128(1)°. The isotypic compounds Sr2PO4I and Ba2PO4I were synthesized, too. Their crystallographic structure was refined by Rietveld analysis. The structure of the three compounds is described and discussed.
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1968
期刊:
Die Naturwissenschaften
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1970
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1970
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1972
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